Blacklist season 3 episode 5
Raymond Reddington and Elizabeth Keen in Blacklist season 3 episode 5NBC

Troubles seem to be never ending for Elizabeth Keen as a bounty is put on Liz's head by a Blacklister in the upcoming chapter of The Blacklist season 3. Episode 5 is titled, Arioch Cain, which will air this Thursday, 29 October at 9pm EST on NBC.

The official synopsis reads as follows:

An enormous bounty is posted for Agent Keen drawing out any number of unknown assassins while the FBI and Reddington join forces to protect her.

Click here to watch the episode via live stream, or you can watch it online by clicking here. A bounty is posted for agent Keen, after which a number of shady assassins surface to take down Liz. But before they get to Liz, the assassins have to go through Red, who will go to any lengths to protect her.

The voice-over in a promo video says, "A Blacklister is taking justice into his own hands, now the whole world is after her" as agent Aram Mojtabai tells the FBI team, "Someone's put a price on agent Keen's head."

The video shows Red telling Liz, "We have to move, now." Agent Ressler is not sure about protecting Keen as she is a fugitive, and says, "We are not going to protect Keen, we are going to arrest her." The promo ends with Red and Liz surrounded by armed men as he says, "Put down the gun Elizabeth."

Can Red save Liz? All will be answered in The Blacklist's new episode airing tonight on NBC.