Bollywood diva and former Miss World, Aishwarya Rai Bachchan, made her first appearance at the 66th annual Cannes Film Festival.

The 39-year-old actress, who is a regular at Cannes, looked gorgeous in a black lace-print Elie Saab Spring 2013 Couture gown, which featured sequined lace embroidery.

Australian actress and jury member Nicole Kidman, who was joined by her husband Keith Urban, looked stunning in a blue, red and black leaf-print L'wren dress. She completed her look with Manolo shoes, Fred Leighton jewels and a Roger Vivier clutch.

American actress Jessica Biel, who came to cheer her husband Justin Timberlake at the world premiere of his latest film, Inside Llewyn Davis, wore a mid-length Marchesa dress with feather underskirt and swirling applique detailing. The 31-year-old finished the look with a serpent necklace from Bvlgari, a diamond-studded clutch bag and Manolo Blahnik shoes.

Meanwhile, her husband, the 32-year-old Friends With Benefits star, looked dapper in a Balenciaga tuxedo, a Cartier watch and vintage Mother Of Pearl cuff links. His co-star, Carey Mulligan, looked chic in a black-and-white Vionnet gown with a front split and a black satin neckline. She completed the red carpet look with Brian Atwood 'Aida' sandals.

Indian actress Vidya Balan opted for a traditional outfit and wore a Sabyasachi golden silk sari. Kirsten Dunst wore a Michael Van Der Ham black and white gown, which featured black and purple velvet detailing and white lace embroidery.

Scroll down to take a look at the hottest looks on the red carpet on fifth day of Cannes Film Festival 2013... 

Indian actress Aishwarya Rai poses on the red carpet as she arrives for the screening of the film
Indian actress Aishwarya Rai poses on the red carpet as she arrives for the screening of the film "Inside Llewyn Davis" in competition during the 66th Cannes Film Festival in Cannes May 19, 2013.Reuters
Actress Jessica Biel poses on the red carpet as she arrives for the screening of the film
Actress Jessica Biel poses on the red carpet as she arrives for the screening of the film "Inside Llewyn Davis" in competition during the 66th Cannes Film Festival in Cannes May 19, 2013.Reuters
Jury member actress Nicole Kidman (R) and her husband Keith Urban pose on the red carpet as they arrive for the screening of the film
Jury member actress Nicole Kidman (R) and her husband Keith Urban pose on the red carpet as they arrive for the screening of the film "Inside Llewyn Davis" in competition during the 66th Cannes Film Festival in Cannes May 19, 2013.Reuters
Bollywood actress Mallika Sherawat poses on the red carpet as she arrives for the screening of the film
Bollywood actress Mallika Sherawat poses on the red carpet as she arrives for the screening of the film "Inside Llewyn Davis" in competition during the 66th Cannes Film Festival in Cannes May 19, 2013.Reuters
Jury Member actress Vidya Balan poses on the red carpet as she arrives for the screening of the film
Jury Member actress Vidya Balan poses on the red carpet as she arrives for the screening of the film "Inside Llewyn Davis" in competition during the 66th Cannes Film Festival in Cannes May 19, 2013.Reuters
Cast members Carey Mulligan (L) and Justin Timberlake pose on the red carpet as they arrive for the screening of the film
Cast members Carey Mulligan (L) and Justin Timberlake pose on the red carpet as they arrive for the screening of the film "Inside Llewyn Davis" in competition during the 66th Cannes Film Festival in Cannes May 19, 2013.Reuters
Actress Kirsten Dunst poses on the red carpet as she arrives for the screening of the film
Actress Kirsten Dunst poses on the red carpet as she arrives for the screening of the film "Inside Llewyn Davis" in competition during the 66th Cannes Film Festival in Cannes May 19, 2013.Reuters
Actress Maudy Koesnadi poses on the red carpet as she arrives for the screening of the film
Actress Maudy Koesnadi poses on the red carpet as she arrives for the screening of the film "Inside Llewyn Davis" in competition during the 66th Cannes Film Festival in Cannes May 19, 2013.Reuters
Actress Jane Fonda poses on the red carpet as she arrives for the screening of the film
Actress Jane Fonda poses on the red carpet as she arrives for the screening of the film "Inside Llewyn Davis" in competition during the 66th Cannes Film Festival in Cannes May 19, 2013.Reuters
French actress Frederique Bel poses on the red carpet as she arrives for the screening of the film
French actress Frederique Bel poses on the red carpet as she arrives for the screening of the film "Inside Llewyn Davis" in competition during the 66th Cannes Film Festival in Cannes May 19, 2013.Reuters
Actress Nadine Labaki poses on the red carpet as she arrives for the screening of the film
Actress Nadine Labaki poses on the red carpet as she arrives for the screening of the film "Inside Llewyn Davis" in competition during the 66th Cannes Film Festival in Cannes May 19, 2013.Reuters
Model and designer Olga Sorokina poses on the red carpet as she arrives for the screening of the film
Model and designer Olga Sorokina poses on the red carpet as she arrives for the screening of the film "Inside Llewyn Davis" in competition during the 66th Cannes Film Festival in Cannes May 19, 2013.Reuters
Lebanese businesswoman Mouna Ayoub poses on the red carpet as she arrives for the screening of the film
Lebanese businesswoman Mouna Ayoub poses on the red carpet as she arrives for the screening of the film "Inside Llewyn Davis" in competition during the 66th Cannes Film Festival in Cannes May 19, 2013.Reuters