Boris Johnson will hold his first meeting with the new European Commission President, Ursula von der Leyen, in London on Wednesday.
The two sides will have just 11 months to settle that agreement following Britain's formal departure from the EU on January 31.
BoE governor, Mark Carney will handover on January 31 after six years in the role.
A final vote on Johnson's separation terms will come when lawmakers return from their Christmas break early next month.
Around 50 MPs, led by Mark Francois of the hardline anti-EU European Research Group, are backing the request.
Top of Johnson's to-do list is a bill to ratify the terms of Britain's exit from the European Union.
Britain is due to leave the European Union on January 31, but will remain in a transitional arrangement until the end of the year.
Queen Elizabeth II will open parliament in a lavish ceremony on Thursday.
Prime Minister Boris Johnson promised to "get Brexit done" by taking Britain out of the European Union by January 31.
The EU earlier imposed duties on imports of subsidised biodiesel from Indonesia.
The veteran socialist blamed the media for helping to cause his century-old party's worst finish since before World War II.
The Parliament will now be free to approve the divorce deal Johnson struck with Brussels so that Britain can leave without any more delays on January 31.
After months of high-level talks, negotiators presented the president with a deal that will see China ramp up its purchases of agricultural goods.
He will be able to get the divorce deal he struck with Brussels through parliament in time to meet the January 31 deadline.
Johnson says Brexit will free up the new government to concentrate on trying to grow the stalled economy.
Johnson's Conservative party had secured 362 seats -- its biggest majority since the heyday of Margaret Thatcher in the 1980s.
An exit poll after voting ended on Thursday night suggested a large majority for Prime Minister Boris Johnson's Conservatives.
The Conservative leader campaigned relentlessly on a promise to "Get Brexit Done", by finally taking Britain out of the European Union next month.
The Conservatives were forecast to win a thumping 368 out of 650 seats in parliament.
Johnson is hoping to regain the Conservative majority lost by his predecessor Theresa May in the last election.
The British prime minister has not been seen publicly with his girlfriend Carrie Symonds in over a month.
The former German defence minister urged lawmakers to approve her 27-strong commission so that she can get to work on December 1.